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Thursday, May 7, 2015

Chemical Equilibrium of Gases

Category: Chemical Engineering Math

"Published in Newark, California, USA"

Consider the following reaction at 1600°C:


When 1.05 moles Br2 are placed in a 2L flask, 2.50% of Br2 undergoes dissociation. Calculate Kp for the reaction.

Solution:

Consider the chemical reaction above


The first thing that we need to do is to get the molarity of Br2 as follows



At equilibrium, the amount of remaining Br2 is



At equilibrium, the amount of Br formed is



Hence, the equilibrium constant of the given reaction is
 
 
 


Since all products and reactants for the given reactions are all gases, then we have to use the formula as follows


where ∆n is the difference between the sum of the coefficients of the products and the sum of the coefficients of the reactants.
 
The universal gas law constant for gmole, atmosphere, liters, and K is.

The absolute temperature of the reaction is
 
 

Therefore, the value of Kp for the given reaction is