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Friday, June 5, 2015

Volumetric Analysis Problems, 10

Category: Chemical Engineering Math

"Published in Newark, California, USA"

A 750.25 mg alloy of nickel was dissolved and treated to remove the impurities. The ammonium solution was treated with 50 mL of 0.1075 M KCN and the excess cyanide required 2.25 mL of 0.00925 M AgNO3. Determine the % Ni in the alloy.

Solution:

If nickel is dissolved in ammonium solution, then nickel is converted into nickel ion in order to remove the impurities. If KCN solution is added to nickel solution, then the chemical reaction is



From the chemical reaction above, we can solve for the weight of nickel as follows
 
 
 
 
 
 

Therefore, the percent of nickel in the alloy is
 
 

Thursday, June 4, 2015

Volumetric Analysis Problems, 9

Category: Chemical Engineering Math

"Published in Newark, California, USA"

A 500 mg sample containing NaCN required 23.50 mL of 0.1255 M AgNO3 to obtain a permanent faint turbidity. Express the result of this analysis as %CN-.

Solution:

If AgNO3 is added to NaCN, then the chemical reaction is

  
From the chemical reaction above, the weight of CN- is  




Therefore, the percent of CN- in a sample is 


Wednesday, June 3, 2015

Volumetric Analysis Problems, 8

Category: Chemical Engineering Math

"Published in Newark, California, USA"

A 1.500 gram sample of impure AlCl3 was dissolved in water and treated with 45.32 mL of 0.1000 M AgNO3 using Mohr Method. Determine its purity. 

Solution:

If AlCl3 solution is treated with AgNO3, then the chemical reaction is 


From the chemical reaction above, the weight of pure AlCl3 is
  




Therefore, the percent of AlCl3 in a sample is