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Monday, September 8, 2014

Stoichiometry Problem - Total Hardness

Category: Chemical Engineering Math

"Published in Newark, California, USA"

"Hard" water contains small amounts of the salt calcium bicarbonate [Ca(HCO3)2] and calcium sulfate [CaSO4, molecular weight = 136 grams/mole]. These react with soap before it has a chance to lather, which is responsible for its cleansing ability. Ca(HCO3)2 is removed by boiling to form insoluble CaCO3. CaSO4 is removed by reaction with washing soda [Na2CO3, molecular weight = 106 grams/mole] according to the following equation:


If the rivers surrounding New York City have a CaSO4 concentration of 1.8 x 10-3 grams/liter, how much Na2CO3 is required to "soften" [remove CaSO4] the water consumed by the city in one day [about 6.8 x 109 liters]? 

Solution:

The first thing that we have to do is to get the amount of CaSO4 in the rivers surrounding New York City as follows 



Moles of CaSO4:



From the given reaction above


Moles of Na2CO3:


Therefore, the amount of Na2CO3 required to "soften" or remove CaSO4 in the rivers surrounding New York City is 



In metric tons, the weight of Na2CO3 is