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Wednesday, October 2, 2013

Stoichiometry Problem - Material Balance, 22

Category: Chemical Engineering Math, Algebra

"Published in Newark, California, USA"

A multiple effect evaporator system has a capacity of processing 1000 kg per day of solid caustic soda when it concentrates weak liquor from 4% to 25% by weight caustic soda. When the same plant is fed with 10% weak liquor and if it is concentrated to 50% (both on weight basis), find the capacity of the plant in terms of solid caustic soda. Assume that the water evaporating capacity to be same in both cases. 

Solution:

The given word problem is about evaporation of caustic soda solution with two cases with the same water evaporating capacity which involves the principles of Stoichiometry. The total amount of a substance in the reactants or incoming ingredients must be equal to the total amount of a substance in the final products. In short, the Law of Conservation of Mass must be followed all the time.  To illustrate the given problem, it is better to draw the flow diagram as follows

Case I:

Photo by Math Principles in Everyday Life

Basis: 1000 kg/day of solid caustic soda on Weak Liquor and Thick Liquor

Let x = be the amount of Weak Liquor
      y = be the amount of Thick Liquor
      z = be the amount of Water Vapor

Overall Material Balance of Multiple Effect Evaporator:



Material Balance of Caustic Soda:



If the amount of solid caustic soda at Weak Liquor and Thick Liquor are the same, then it follows that



We can solve for the value of x as follows





We can solve for the value of y as follows





Substitute the values of x and y to the first equation in order to solve for the value of z which is the amount of water vapor as follows







Case II:

The amount of water evaporated in Case I is the same as in Case II. 


Photo by Math Principles in Everyday Life



Basis: 21000 kg/day of Water Vapor

Let x = be the amount of Weak Liquor
      y = be the amount of Thick Liquor

Overall Material Balance of Multiple Effect Evaporator:


Material Balance of Solid Caustic Soda:



Substitute the value of x to the first equation, we have





Therefore, the capacity of the plant in terms of solid caustic soda or the amount of solid caustic soda is